Do you love licorice - or hate it? Could be allsorts of reasons for that

Science is finding out what makes licorice so pungent.

Licorice allsorts

Science has figured out that distinctive smell. Source: Flickr / JonoTakesPhotos

There are foods that can split families, or even just couples. Love it or hate it foods. Marmite (and the vegetarian alternative, Vegemite) is one. Then there’s Brussels sprouts, blue cheese, chilli peppers, coriander (cilantro), tomatoes (especially the cooked variety) … and licorice.
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Personally, I’ve always liked licorice - aka liquorice - but who feel very differently about it. There are known to be genetic reasons behind a dislike of some foods or but no one has established this for licorice.

Licorice has a long history; the root of the plant Glycyrrhiza glabral has been used medicinally for more than 4000 years.

Licorice has anti-inflammatory, antibacterial and antiviral properties and has been used, notably in traditional Chinese medicine, for the treatment of and liver disorders, .

Among its less beneficial effects on the body is , caused by the glycyrrhizic acid it contains, if you eat too much. Through its interaction with the hormone aldosterone, it causes reabsorption of sodium and excretion of potassium, in an increase in sodium levels and a decrease in potassium levels – one symptom of which is muscular weakness. And pregnant women have been because it pushes up levels of cortisol, the stress hormone. A study upon which this advice is based drew on several hundred children born in Finland in 1998. They found that mothers who ate more salmiak, licorice with added ammonium chloride, gave birth to children who were more likely to have lower IQs and to suffer from ADHD.

Sweet smell of success

We more usually think of licorice in confectionery, where an extract of raw licorice is heated up with other ingredients such as flour, treacle, flavourings and colourings to produce a sweet, thickened product. In Britain, it is closely associated with the Yorkshire town of Pontefract, where it was first grown nearly 1000 years ago after it was . In 1760, an apothecary named Charles Dunhill “Pontefract cakes”, flat, circular sweets. Dark salty licorice is hugely popular in northern European countries such as Holland and Sweden.

Licorice is used as a flavouring in substances as diverse as tea and tobacco, and in drinks like the Egyptian erk sous and the French pastis. The sweetness of licorice is principally due to the glycyrrhizin (or glycyrrhizic acid), which is around 40 times sweeter than sucrose (table sugar).
Smashed liquorice meringues with berries & chocolate cream
Source: BBC Books / James Murphy
Use the distinctive flavour in 

Sweet smell of success

The aromas of and are due to a blend of chemicals, recently identified by a research group in Munich, led by Peter Schieberle, a distinguished flavour scientist.

The team achieved this by first separating the complex mixtures of chemicals present in the licorice, and then identifying each one by spectroscopic techniques. Aroma experts then examined each compound to find which of the molecules present actually contributed towards it (around 50). Finally, they reconstituted a mixture of these molecules, each present at its “natural” concentration, to see if the mixture had the characteristic licorice smell (it did).

So there is no single molecule which has a licorice smell by itself; what we smell is a blend of odours from all these molecules, which our brain “integrates”. The molecules (also found in aniseed, fennel and star anise) and estragole (also found in tarragon) supply an “aniseed” note, but there are many other important compounds that contribute, including 1,8-cineole , 2-acetyl-1-pyrroline, responsible for the “popcorn” note of many cereal products like bread and rice, and a number of aldehydes such as (E,Z)-2,6-nonadienal (found in cucumbers).

The heat-processed licorice extract has many molecules in common with raw licorice, but like maltol, which contributes a caramel note, and 3-hydroxy-4,5-dimethylfuran-2(5H)-one (sotolone), also with a caramel note at low concentrations and which is responsible for the flavour of raw cane sugar.

Many of the extra molecules are generated in the heating process from reactions, such as those between sugars and amino acids present in the raw liquorice root.

So enjoy your licorice – if you do. Just don’t overdo it.

, Senior Lecturer in Chemistry, . This article was originally published on . Read the .

Lead image by  via Flickr. 


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4 min read
Published 14 March 2017 11:29am
Updated 23 November 2017 2:40pm
By Simon Cotton
Source: The Conversation


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